2002
DOI: 10.1590/s0100-40422002000300005 View full text |Buy / Rent full text
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Abstract: Recebido em 5/1/01; aceito em 14/11/01 THERMAL DECOMPOSITION OF PINACOLONE DIPEROXIDE (3,6-ditertbutyl-3,6-dimethyl-1,2,4,5-tetraoxacyclohexane) IN 2-METHOXYETHANOL SOLUTION. The thermal decomposition reaction of pinacolone diperoxide (DPP; 0.02 mol kg -1 ) in 2-methoxyethanol solution studied in the temperature range of 110.0-150.0 °C, follows a first-order kinetic law up to at least 50% DPP conversion. The organic products observed were pinacolone, methane and tert-butane. A stepwise mechanism of decompositi… Show more

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