IntroductionWurtzite (WZ) GaN-based quantum wells (QWs) have received a great deal of attention in recent years for their potential application in blue-green optoelectronic devices [1]. The Hamiltonian based on the k.p method, for the conduction and valence-band structures of the GaN-based quantum wells have been derived [2] and applied to strained GaN quantum-well lasers [3]. The hole effective mass of WZ GaN-based QWs with the (0001) crystal orientation is significantly larger than that of conventional zincblende (ZB) crystals used in semiconductor lasers, such as GaAs and InP. In addition, it has been shown that the introduction of biaxial strain into the (0001)-plane of WZ GaNbased QWs does not effectively reduce the effective masses in the transverse direction [2][3][4][5][6][7][8]. In the conventional ZB crystals, on the other hand, a biaxial compressive strain in the QW structure reduces the in-plane effective mass of the top heavy-hole band and the threshold current density of a semiconductor laser [9]. WZ GaN-based QWs with the (0001) crystal orientation require higher carrier densities to generate optical gain compared to ZB GaAs-based QWs [10,11]. In addition, it was found that the GaN-based QW structures have a large internal electric field due to piezoelectric (PZ) and spontaneous (SP) polarizations [12][13][14][15]. This internal field in the QW structures causes the intrinsic quantum confined Stark effect, resulting in a red shift of the transition energy and a decrease in the radiative transition probability. The large internal field is expected to strongly affect the electronic and optical properties of GaNbased QW structures. Thus, the control of the internal field and the reduction of the effective mass is very important for the realization of high-performance, GaN-based devices.As an additional parameter for band-structure engineering, the crystal orientation effect on characteristics of WZ GaN-based QW lasers has been studied for the realization of high-performance devices [16][17][18][19][20]. In particular, the