2008
DOI: 10.2174/138527208785909592
|View full text |Cite
|
Sign up to set email alerts
|

Abstract: This review presents developments in the young field of dehydrogenative coupling reactions of phosphines. Catalytic phosphorus-element bond formation via dehydrocoupling has rapidly expanded since the first discoveries in the mid 1990s. A survey of the available catalysts, P-P and P-E products, and mechanistic understanding is presented with emphasis on the emerging synthetic applications of this reaction.

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...
4

Citation Types

2
41
0

Year Published

2010
2010
2021
2021

Publication Types

Select...
4
1

Relationship

0
5

Authors

Journals

citations
Cited by 73 publications
(43 citation statements)
references
References 118 publications
(236 reference statements)
2
41
0
Order By: Relevance
“…Calculations of representative extrema with Ph 2 SnH 2 in place of SnH 4 gave similar results. The calculations are therefore in good agreement with experiment, in that insertion into the HfÀSn bond is preferred for unhindered stannanes (such as SnH 4 and Ph 2 SnH 2 ). Although bulky stannanes were not considered, it is likely that s-bond metathesis would be even more disfavored in such cases.…”
Section: Electrophilic Dsupporting
confidence: 76%
See 4 more Smart Citations
“…Calculations of representative extrema with Ph 2 SnH 2 in place of SnH 4 gave similar results. The calculations are therefore in good agreement with experiment, in that insertion into the HfÀSn bond is preferred for unhindered stannanes (such as SnH 4 and Ph 2 SnH 2 ). Although bulky stannanes were not considered, it is likely that s-bond metathesis would be even more disfavored in such cases.…”
Section: Electrophilic Dsupporting
confidence: 76%
“…[9] In parallel, the a-elimination of methylene from [Cp' 2 Ce(CH 2 X)] (Cp' = 1,2,4-tBu 3 C 5 H 2 ; X = F, Cl, Br, I, OMe, NMe 2 ) in the reaction of [Cp' 2 CeH] with CH 3 X to form [Cp' 2 CeX] and CH 4 shows that the formation of carbene occurs in the presence of electron-withdrawing X groups . [10] Interestingly, then, there appears to be two fundamental processes associated with dehydrocoupling of main-group compounds as catalyzed by early transition metals: s-bond metathesis and migratory deinsertion of low-valent species (and subsequent reinsertion into the appropriate bond).…”
Section: Electrophilic Dmentioning
confidence: 99%
See 3 more Smart Citations