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Cited by 296 publications
(206 citation statements)
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“…Thus, viscosity increase from ACN to PC leads to a decrease in the intensity of the peak current. Moreover, the current intensity is dependent on the diffusion coefficient of the compounds in each solvent which could explain the changes in current intensities [25]. Additionally, one can see in Table 1 that the oxidation potential peaks of the two compounds also depend on the International Journal of Electrochemistry solvent in which the studies were carried out.…”
Section: Electrochemistry Of the Uncoordinated Chemosensorsmentioning
confidence: 99%
“…Thus, viscosity increase from ACN to PC leads to a decrease in the intensity of the peak current. Moreover, the current intensity is dependent on the diffusion coefficient of the compounds in each solvent which could explain the changes in current intensities [25]. Additionally, one can see in Table 1 that the oxidation potential peaks of the two compounds also depend on the International Journal of Electrochemistry solvent in which the studies were carried out.…”
Section: Electrochemistry Of the Uncoordinated Chemosensorsmentioning
confidence: 99%
“…It was also found that the peak currents are essentially constant for several cycles. These results indicated that there are no chemical reactions coupled with the electron transfer [15]. Furthermore, the reduction potential E pc was found to depend on the scan rate.…”
Section: Electro-reduction Studymentioning
confidence: 87%
“…The redox potential data of all the complexes measured in water is given in Table 1. Generally, the redox potentials are better expressed by E 1/2 than by the anodic peak, E pa , or cathodic peak, E pc , potentials, because both E pa and E pc change with the scan rate, whereas E 1/2 is independent of the scan rate [15]. The redox potential of the Co(III)/Co(II) couple was determined according to the equation [16] …”
Section: Electro-reduction Studymentioning
confidence: 99%
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“…According to the Stokes-Einstein equation D is inversely proportional toη. 41 Thus, it is deduced that in more viscous solutions the diffusion will be slower. At 25 0 C the viscosity of DMSO , where E 0 is the standard redox potential, n the total number of electrons involved in the electrochemical reaction, F the Faraday constant, A the area of the electrode and C ∞ the concentration of…”
Section: Auclmentioning
confidence: 99%