2013 IEEE International Interconnect Technology Conference - IITC 2013
DOI: 10.1109/iitc.2013.6615551
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CVD Mn-based self-formed barrier for advanced interconnect technology

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Cited by 8 publications
(3 citation statements)
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“…Mn-based self-formed barrier (SFB) is an attractive alternative technique from RC performance point of view. Previous studies based on PVD Cu-Mn alloy seed and CVD depositions of Mn from various precursors have been demonstrated alternative route for SFB formation [ 273 , 274 , 275 , 276 ]. Nogami et al from IBM [ 252 ] showed Line R cross-over point to alternative metals depends on barrier/wetting layer thickness.…”
Section: Metal Materials Interconnectmentioning
confidence: 99%
“…Mn-based self-formed barrier (SFB) is an attractive alternative technique from RC performance point of view. Previous studies based on PVD Cu-Mn alloy seed and CVD depositions of Mn from various precursors have been demonstrated alternative route for SFB formation [ 273 , 274 , 275 , 276 ]. Nogami et al from IBM [ 252 ] showed Line R cross-over point to alternative metals depends on barrier/wetting layer thickness.…”
Section: Metal Materials Interconnectmentioning
confidence: 99%
“…Figure 3 shows a transmission electron microscopy (TEM) image of typical crevice corrosion, which happened between the copper and TaN barrier metal films and is often seen in conference papers reported by device makers. [20][21][22] One might think that this is a galvanic corrosion (it will be discussed in Sect. 9), but it also happens without the TaN film, 21,23) so it seems to occur owing to crystallographically weak points of copper films at the interface with the barrier metal film or intermetal dielectric (IMD) film.…”
Section: Crevice Corrosionmentioning
confidence: 99%
“…[20][21][22] One might think that this is a galvanic corrosion (it will be discussed in Sect. 9), but it also happens without the TaN film, 21,23) so it seems to occur owing to crystallographically weak points of copper films at the interface with the barrier metal film or intermetal dielectric (IMD) film.…”
Section: Crevice Corrosionmentioning
confidence: 99%