Crystallographic analysis of a series of inorganic compounds

Abstract

Crystallographic analysis of a series of inorganic compounds{ { S V Borisov, S A Magarill, N V Pervukhina A V Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences prosp. Akademika Lavrentieva 3, 630090 Novosibirsk, Russian Federation Contents { This review continues a series of reviews dedicated to the International Year of Crystallography [see Russ. Chem. Rev. 83 (12) (2014)]. Russian Chemical Reviews 84 (4) 393 ± 421 (2015) # 2015 Russian Academy of Sciences and Turpion Ltd } Figures 2 ± 7, 8 c, 15, 16, 23, 26 and 28 were prepared by the authors specially for this review.

Crystal-Forming Functions of Glide Planes in the Structural Organization of a Number of (Pb, Bi)-Containing Sulfides

“…4 ɩɪɢɜɟɞɟɧɵ ɞɚɧɧɵɟ ɨ ɤɚɬɢɨɧɧɵɯ Ɍ ɚ ɛ ɥ ɢ ɰ ɚ 4 ȼɢɤɢɧɝɢɬ. Ɋɚɫɱɟɬɧɵɟ ɡɧɚɱɟɧɢɹ ɧɚɢɛɨɥɟɟ ɢɧɬɟɧɫɢɜɧɵɯ ɫɬɪɭɤɬɭɪɧɵɯ ɚɦɩɥɢɬɭɞ F hkl , ɜɵɱɢɫɥɟɧɧɵɯ ɩɨ ɤɨɨɪɞɢɧɚɬɚɦ ɜɫɟɯ ɚɬɨɦɨɜ ɫɬɪɭɤɬɭɪɵ Ʉɚɤ ɭɠɟ ɛɵɥɨ ɩɨɤɚɡɚɧɨ ɪɚɧɟɟ [ 2,3 ], ɜ sɬɚɛɥɟɬɱɚɬɵɯs ɫɬɪɭɤɬɭɪɚɯ ɫɭɥɶɮɢɞɨɜ ɡɚ ɫɱɟɬ ɜɚɤɚɧɬɧɵɯ ɭɡɥɨɜ ɜ ɤɚɬɢɨɧɧɵɯ ɢ ɚɧɢɨɧɧɵɯ ɩɨɞɪɟɲɟɬɤɚɯ, ɤɨɬɨɪɵɯ ɜ ɧɢɯ ɪɨɜɧɨ ɩɨɥɨɜɢɧɚ ɨɬ ɨɛɳɟɝɨ ɱɢɫɥɚ, ɢɦɟɟɬɫɹ ɜɨɡɦɨɠɧɨɫɬɶ ɪɚɡɧɵɯ ɜɚɪɢɚɧɬɨɜ ɪɚɡɦɟɳɟɧɢɹ ɚɬɨɦɨɜ, ɱɬɨɛɵ: ɢɥɢ ɫɨɡɞɚɬɶ ɛɨɥɟɟ ɩɪɢɟɦɥɟɦɨɟ ɤɨɨɪɞɢɧɚɰɢɨɧɧɨɟ ɨɤɪɭɠɟɧɢɟ, ɢɥɢ ɩɨɜɵɫɢɬɶ ɫɢɦɦɟɬɪɢɸ ɫɬɪɭɤɬɭɪɵ (ɧɚɩɪɢɦɟɪ, ɦɢɤɪɨɞɜɨɣɧɢɤɨɜɚɧɢɟ ɜ ɫɬɪɭɤɬɭɪɚɯ ɥɢɥɥɢɚɧɢɬɚ ɢ ɯɟɣɪɨɜɫɤɢɢɬɚ [ 3,10 ]). ȼ ɫɬɪɭɤɬɭɪɟ ɜɢɤɢɧɝɢɬɚ ɚɧɢɨɧɵ ɫɨɡɞɚɥɢ ɩɪɢɡɦɚɬɢɱɟɫɤɨɟ ɨɤɪɭɠɟɧɢɟ ɞɥɹ ɨɞɧɨɝɨ ɢɡ ɤɚɬɢɨɧɨɜ, ɨɛɪɚɡɨɜɚɜ ɧɚ ɡɟɪɤɚɥɶɧɵɯ ɩɥɨɫɤɨɫɬɹɯ ɬɪɟɭɝɨɥɶɧɢɤ ɢɡ ɛɥɢɡɤɨɥɟɠɚɳɢɯ ɚɧɢɨɧɨɜ ɫɟɪɵ (ɫɦ.…”

“…Ɋɚɫɫɦɨɬɪɟɧɧɵɟ ɫɬɪɭɤɬɭɪɵ ɩɨɞɬɜɟɪɞɢɥɢ ɪɚɧɟɟ ɭɫɬɚɧɨɜɥɟɧɧɵɟ ɮɚɤɬɵ ɧɟɡɚɜɢɫɢɦɨɝɨ ɭɩɨɪɹɞɨɱɟɧɢɹ ɤɚɬɢɨɧɨɜ ɢ ɚɧɢɨɧɨɜ ɫɨɛɫɬɜɟɧɧɵɦɢ ɩɨɞɪɟɲɟɬɤɚɦɢ ɢ ɤɨɧɟɱɧɨ ɫɚɦ ɮɟɧɨɦɟɧ ɩɫɟɜɞɨɬɪɚɧɫɥɹɰɢɨɧɧɵɯ ɭɩɨɪɹɞɨɱɟɧɢɣ ɜ ɤɪɢɫɬɚɥɥɢɱɟɫɤɢɯ ɫɬɪɭɤɬɭɪɚɯ ɩɪɢ ɫɚɦɵɯ ɪɚɡɧɨɨɛɪɚɡɧɵɯ ɚɬɨɦɧɵɯ ɫɨɫɬɚɜɚɯ [ 3,10 ]. ɂɡɥɸɛɥɟɧɧɵɟ ɠɟ ɩɪɢɪɨɞɨɣ ɩɥɨɫɤɨɫɬɢ ɫɤɨɥɶɡɹɳɟɝɨ ɨɬɪɚɠɟɧɢɹ ɧɚ ɩɟɪɜɵɣ ɜɡɝɥɹɞ ɤɚɤ ɛɭɞɬɨ ɡɚɬɪɭɞɧɹɸɬ ɩɪɨɰɟɫɫ ɭɩɨɪɹɞɨɱɟɧɢɹ ɚɬɨɦɨɜ ɫɢɫɬɟɦɚɦɢ ɩɚɪɚɥɥɟɥɶɧɵɯ ɪɚɜɧɨɭɞɚɥɟɧɧɵɯ ɩɥɨɫɤɨɫɬɟɣ, ɬɚɤ ɤɚɤ ɜɜɨɞɹɬ ɞɨɩɨɥɧɢɬɟɥɶɧɵɟ ɩɥɨɫɤɨɫɬɢ (ɜ ɬɨɦ ɫɥɭɱɚɟ, ɟɫɥɢ ɧɟɬ ɞɨɦɢɧɢɪɭɸɳɢɯ ɫɢɫɬɟɦ ɢɡ ɩɥɨɫɤɨɫɬɟɣ, ɫɜɹɡɚɧɧɵɯ ɷɬɨɣ ɫɢɦɦɟɬɪɢɟɣ).…”

“…ɋɨɡɞɚɟɬɫɹ ɜɩɟɱɚɬɥɟɧɢɟ, ɱɬɨ ɜɢɧɬɨɜɵɟ ɨɫɢ ɢ ɩɥɨɫɤɨɫɬɢ ɫɤɨɥɶɡɹɳɟɝɨ ɨɬɪɚɠɟɧɢɹ -sɨɬɤɪɵɬɵɟs ɷɥɟɦɟɧɬɵ ɫɢɦɦɟɬɪɢɢ -ɛɨɥɟɟ ɩɪɟɞɩɨɱɬɢɬɟɥɶɧɵ ɜ ɩɪɨɰɟɫɫɚɯ ɤɪɢɫɬɚɥɥɢɡɚɰɢɢ, ɱɟɦ ɨɫɬɚɥɶɧɵɟ ɨɩɟɪɚɰɢɢ (ɜ C2/m, ɤɚɤ ɢɡɜɟɫɬɧɨ, ɰɟɧɬɪɢɪɭɸɳɚɹ ɬɪɚɧɫɥɹɰɢɹ ɨɛɪɚɡɭɟɬ sɨɬɤɪɵɬɵɟs ɷɥɟɦɟɧɬɵ, ɱɟɪɟɞɭɸɳɢɟɫɹ ɫ ɬɢɬɭɥɶɧɵɦɢ 2 ɢ m). ɂɫɩɨɥɶɡɭɹ ɫɜɨɣ ɨɩɵɬ ɤɪɢɫɬɚɥɥɨɝɪɚɮɢɱɟɫɤɨɝɨ ɚɧɚɥɢɡɚ ɫɬɪɭɤɬɭɪ ɫɭɥɶɮɢɞɨɜ, ɜ ɬɨɦ ɱɢɫɥɟ ɢ ɜɟɫɶɦɚ ɪɚɫɩɪɨɫɬɪɚɧɟɧɧɵɯ sɬɚɛɥɟɬɱɚɬɵɯs -ɫ ɡɟɪɤɚɥɶɧɵɦɢ ɩɥɨɫɤɨɫɬɹɦɢ ɫɢɦɦɟɬɪɢɢ ɢ ɩɟɪɩɟɧɞɢɤɭɥɹɪɧɵɦɢ ɤ ɧɢɦ ɤɨɪɨɬɤɢɦɢ (a4 Å) ɬɪɚɧɫɥɹɰɢɹɦɢ [ 2,3 ] -ɦɵ ɜ ɞɚɧɧɨɣ ɪɚɛɨɬɟ ɪɚɫɫɦɨɬɪɢɦ ɫɬɪɭɤɬɭɪɨɨɛɪɚɡɭɸɳɭɸ ɪɨɥɶ ɨɬɤɪɵɬɵɯ ɨɩɟɪɚɰɢɣ ɫɢɦɦɟɬɪɢɢ ɧɚ ɪɹɞɟ ɯɚɪɚɤɬɟɪɧɵɯ ɩɪɢɦɟɪɨɜ.…”

CRYSTALLOGRAPHIC ANALYSIS OF SULFIDES RELATED TO BISMUTHINITE Bi2S3

“…ȼɫɟ ɨɧɢ ɢɦɟɸɬ ɡɟɪɤɚɥɶɧɵɟ ɩɥɨɫɤɨɫɬɢ ɫɢɦɦɟɬɪɢɢ, ɩɟɪɩɟɧɞɢɤɭɥɹɪɧɵɟ ɤɨɪɨɬɤɨɣ (a4 Å) ɬɪɚɧɫɥɹɰɢɢ, ɬ.ɟ. sɬɚɛɥɟɬɱɚɬɵɟs ɩɨ ɧɚɲɢɦ ɩɪɟɞɫɬɚɜɥɟɧɢɹɦ [ 4,5 ]. Ⱦɜɟ ɞɪɭɝɢɟ ɬɪɚɧɫɥɹɰɢɢ ɢɯ ɪɨɦɛɢɱɟɫɤɢɯ ɷɥɟɦɟɧɬɚɪɧɵɯ ɹɱɟɟɤ ɤɪɚɬɧɵ a11,5 Å, ɩɪɢɱɟɦ ɨɞɧɚ ɢɡ ɞɜɭɯ ɬɪɚɧɫɥɹɰɢɣ ɪɚɜɧɚ ɷɬɨɣ ɜɟɥɢɱɢɧɟ.…”

“…Ɍɚɤɢɟ ɡɚɦɟɳɟɧɢɹ ɪɟɚɥɢɡɭɸɬɫɹ ɫ ɫɨɯɪɚɧɟɧɢɟɦ ɡɚɪɹɞɚ ɜ ɤɚɬɢɨɧɧɨɣ ɦɚɬɪɢɰɟ ɢ, ɫɥɟɞɨɜɚɬɟɥɶɧɨ, ɫ ɜɨɡɦɨɠɧɨɫɬɶɸ ɫɨɯɪɚɧɟɧɢɹ ɤɨɧɮɢɝɭɪɚɰɢɢ ɢ ɫɨɫɬɚɜɨɜ ɦɚɬɪɢɰɵ ɚɧɢɨɧɧɨɣ. Ɉɰɟɧɢɬɶ ɪɨɥɶ ɤɪɢɫɬɚɥɥɨɝɪɚɮɢɱɟɫɤɢɯ ɢ ɤɪɢɫɬɚɥɥɨɯɢɦɢɱɟɫɤɢɯ ɮɚɤɬɨɪɨɜ ɜ ɫɬɚɛɢɥɶɧɨɫɬɢ ɷɬɢɯ ɫɬɪɭɤɬɭɪ ɦɨɠɧɨ ɩɨ ɪɟɡɭɥɶɬɚɬɚɦ ɢɯ ɤɪɢɫɬɚɥɥɨɝɪɚɮɢɱɟɫɤɨɝɨ ɚɧɚɥɢɡɚ [ 5,7 ]. ɉɨɞ ɤɪɢɫɬɚɥɥɨɝɪɚɮɢɱɟɫɤɢɦɢ ɮɚɤɬɨɪɚɦɢ, ɤɚɤ ɢ ɪɚɧɟɟ, ɛɭɞɟɦ ɩɨɧɢɦɚɬɶ ɨɫɨɛɟɧɧɨɫɬɢ ɭɩɨɪɹɞɨɱɟɧɢɹ ɩɨɡɢɰɢɣ ɚɬɨɦɨɜ ɫɟɦɟɣɫɬɜɚɦɢ ɩɚɪɚɥɥɟɥɶɧɵɯ ɪɚɜɧɨɭɞɚɥɟɧɧɵɯ ɩɥɨɫ-Ɍ ɚ ɛ ɥ ɢ ɰ ɚ 1 ɉɪɢ ɨɛɫɭɠɞɟɧɢɢ ɷɬɢɯ ɩɪɨɛɥɟɦ ɧɟɨɛɯɨɞɢɦɨ ɢɦɟɬɶ ɜ ɜɢɞɭ, ɱɬɨ sɠɟɫɬɤɚɹs ɦɚɬɟɦɚɬɢɱɟɫɤɚɹ ɬɪɚɤɬɨɜɤɚ ɫɬɪɟɦɥɟɧɢɹ ɤ ɦɚɤɫɢɦɚɥɶɧɨɣ ɫɢɦɦɟɬɪɢɢ ɫ ɰɟɥɶɸ ɫɨɤɪɚɳɟɧɢɹ ɫɬɟɩɟɧɟɣ ɫɜɨɛɨɞɵ ɨɛɪɚɡɭɸɳɢɯ ɫɬɪɭɤɬɭɪɭ ɨɛɴɟɤɬɨɜ ɨɬɥɢɱɚɟɬɫɹ ɨɬ ɬɪɚɤɬɨɜɤɢ ɷɧɟɪɝɟɬɢɱɟɫɤɨɣ, ɞɨɩɭɫɤɚɸɳɟɣ ɡɚɦɟɬɧɵɟ ɨɬɤɥɨɧɟɧɢɹ ɨɬ ɢɞɟɚɥɶɧɵɯ ɫɢɦɦɟɬɪɢɱɧɵɯ ɤɨɧɮɢɝɭɪɚɰɢɣ, ɩɪɢ ɤɨɬɨɪɵɯ ɷɧɟɪɝɟɬɢɱɟɫɤɢɣ ɜɵɢɝɪɵɲ ɟɳɟ ɢɦɟɟɬ ɦɟɫɬɨ.…”