Structure D 2000Crystal Structure, Vibrational Spectrum and Thermal Behavior of the Ammonium Hexathiohypodiphosphate Dihydrate (NH 4 ) 4 P 2 S 6 ·2H 2 O. -The title compound crystallizes in the monoclinic space group P21/c with Z = 4 (single crystal XRD). The structure contains isolated, ethane-like P2 anions with staggered conformation, cation, and water molecules, all involved in an extended hydrogen network. -(GJIKAJ*, M.; BROCKNER, W.
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