Passive
radiative cooling is of great significance for energy-saving
and global carbon neutrality because of its zero energy consumption,
no pollution, and low cost. To achieve radiative cooling, minimum
absorption in solar radiation and maximum emission in the sky window
are required. In this work, we have developed an all-season full-daytime
subambient radiative cooler based on Ca3(PO4)2-acrylic paint, which shows an exceptional solar reflectance
of 97.6% and a high sky window emissivity of 0.96. The 5.6 eV bandwidth
and 9.3 μm phonon resonance enable Ca3(PO4)2 to efficiently reflect solar flux and dissipate infrared
emission through the atmospheric window. The field tests during summer
indicate that the surface temperature is more than 18 °C below
ambient temperatures on average, and a net cooling power of 95 W/m2 was obtained during daytime. At noon, with a summit solar
radiation intensity of 900 W/m2, it remains at ∼38
°C below ambient temperature. Furthermore, during winter, the
temperature of the Ca3(PO4)2 paint
drops to as low as −9 °C, which is 16 °C lower than
the ambient temperature, and an average cooling power of 60 W/m2 was obtained. The paint shows a standard figure of merit
of 0.72, which is among the highest of radiative cooling solutions.