Controlled release fertilizers coated by alkylamine-poly (tannic acid) building block with tunable wettability via spraying co-deposition

Sun, Meizhou; Zheng, Jie; Liu, Xinghuan; Yu, Tingting; Zhang, Hengfei; Yang, Wenda; Wang, Rongjie; Jia, Xin

doi:10.1016/j.eurpolymj.2021.110902

Cited by 5 publications

(4 citation statements)

References 49 publications

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“…All peaks are well-matched with previously reported values. 35,36,[43][44][45]50,61 All peaks due to MBAA increase with the cross-linker MBAA amount increase in all types of membranes. On the other hand, the peaks due to APTA do not change much with increasing MBAA amount, which indicates APTA and MBAA incorporation into the PA polymer matrix with expected ratios.…”

Section: Membrane Preparation and Characterizationmentioning

confidence: 96%

“…Quaternary ammonium and imidazole cation-containing AEMs would be better candidates for harsh solvent environments. Quaternary ammonium cation-containing monomer (3-acrylamidopropyl) trimethylammonium chloride (APTA) has been used in many polymers and membranes. − Polymer backbone for AEMs have commonly been based on polystyrene, poly arylene sulfone, polyphenylene oxide (PPO), polyether imide, polyether ether ketone, polybenzimidazole, copolymers from vinyl monomers, and grafted fluoropolymers. To this date, all reported membranes struggle in terms of stability in non-aqueous solvents and require further investigation. − Recently, our group showed that polyethylene-based AEM can block crossover with 88% capacity retention for a 1000 cycle battery test.…”

Section: Introductionmentioning

confidence: 99%

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Phenyl Acrylate-Based Cross-Linked Anion Exchange Membranes for Non-aqueous Redox Flow Batteries

Mazumder

Jadhav

2023

ACS Mater. Au

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Redox flow batteries (RFBs) are of recent interest to store harvested renewable energy for improving grid reliability and utilization. In this study, we synthesized and characterized a series of phenyl acrylate-based UV-cross-linked anion exchange membranes (AEMs) and explored the performance of these AEMs in a model non-aqueous RFB under model conditions. Infrared spectroscopy was utilized to confirm the incorporation of ion carriers in the phenyl acrylate backbone. The electrochemical performance was compared with the commercial Fumasep membrane Fuma-375 based on high stability in non-aqueous solvents, high permeability to the charge-carrying ion, low resistance, low crossover of the redox-active molecules, and low cost. Our results show 55% total capacity retention through 1000 charge/discharge cycles because of low crossover as compared to the Fumasep commercial membrane which retained only 28% capacity. This result is promising in understanding and developing next-generation AEMs for non-aqueous RFBs and other electrochemical systems utilizing organic solvents.

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Section: Membrane Preparation and Characterizationmentioning

confidence: 96%

Section: Introductionmentioning

confidence: 99%

Phenyl Acrylate-Based Cross-Linked Anion Exchange Membranes for Non-aqueous Redox Flow Batteries

Mazumder

Jadhav

2023

ACS Mater. Au

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“…39 To control the wettability of the coating and tune nutrient release, alkylamine−poly(tannic acid) building blocks were prepared as coating materials for controlled-release fertilizers. 40 The length of the alkyl chain in alkylamines plays a crucial role in controlling the wettability and rate of nutrient release.…”

Section: ■ Pda-based Fertilizermentioning

confidence: 99%

“…The hydrophobic octadecylamine–polyphenol-coated urea was prepared using a one-step spraying co-deposition approach for controlled nutrient release (Figure ). To control the wettability of the coating and tune nutrient release, alkylamine–poly(tannic acid) building blocks were prepared as coating materials for controlled-release fertilizers . The length of the alkyl chain in alkylamines plays a crucial role in controlling the wettability and rate of nutrient release.…”

Section: Tannic-acid-based Fertilizermentioning

confidence: 99%

Recent Development of Versatile Polyphenol Platforms in Fertilizers and Pesticides

Wang

Liu

2023

J. Agric. Food Chem.

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The utilization of agrochemicals has been of significant importance in both the cultivation and disease control of crops. The development of advanced agrochemicals that are both effective and eco-friendly has been made possible through the use of slow delivery platforms and surface modification technology. Inspired by the nature of mussel adhesion, polyphenolic platforms with versatile properties have been extensively employed in various applications, including agro-food, owing to their ability to flexibly modulate chemical and surface characteristics. This mini-review highlights the development of polyphenols, such as polydopamine and tannic acid, in the field of agrochemicals, particularly in the design and production of novel fertilizers and pesticides. The synthetic approach, active ingredient release performance, foliar adhesion, and design of polyphenolic-based agrochemicals in recent years have been discussed to explore their potential applications and limitations. We believe that utilizing versatile polyphenolic materials and their characteristics for agro-food applications can provide innovative ideas and suggestions for developing novel agrochemicals suitable for modern and sustainable horticulture and agriculture.

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Improvement of bio-based polyurethane and its optimal application in controlled release fertilizer

Dun

Jariwala

et al. 2022

Journal of Controlled Release

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Controlled release fertilizers coated by alkylamine-poly (tannic acid) building block with tunable wettability via spraying co-deposition

Cited by 5 publications

References 49 publications

Phenyl Acrylate-Based Cross-Linked Anion Exchange Membranes for Non-aqueous Redox Flow Batteries

Phenyl Acrylate-Based Cross-Linked Anion Exchange Membranes for Non-aqueous Redox Flow Batteries

Recent Development of Versatile Polyphenol Platforms in Fertilizers and Pesticides

Improvement of bio-based polyurethane and its optimal application in controlled release fertilizer

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