Controlled growth of narrowly dispersed nanosize hexagonal MOF rods from Mn(iii)–porphyrin and In(NO3)3 and their application in olefin oxidation

Abstract

A new class of narrowly dispersed nanosize hexagonal MOF rods from Mn(III)-porphyrin and In(III) was obtained. The length of MOF rods was controlled by simple change of reaction times. Furthermore, the oxidation of styrene has been successfully demonstrated with Mn(III)-porphyrin MOF rods and their reusability has been also tested.

Simple preparation of Pd-NP/polythiophene nanospheres for heterogeneous catalysis

“…Of the past few decades has yielded enormous research efforts in functional metallic nanoparticles (NPs) [1][2][3][4], transition metal oxide-based NPs [5][6][7][8], and coordination polymer-based NPs [9][10][11]. General preparation methods of metallic NPs often require a reducing agent (such as sodium citrate, ascorbic acid, NaBH 4 , or hydrazine hydrate) for the metallic precursors and suitable surface capping ligands to control the dimension and shape [12][13][14][15][16].…”

Size‐ and Shape‐Controlled Synthesis of Hexagonal Bipyramidal Crystals and Hollow Self‐Assembled Al‐MOF Spheres

“…However, the sizeand shape-controlled synthesis of MOFs has remained largely unexplored. Although a few reports have recently been published, [17][18][19][20][21][22][23][24][25][26] an effective level of control over particle size and shape has not yet been accomplished.…”

Impact of metalloporphyrin‐based porous coordination polymers on catalytic activities for the oxidation of alkylbenzene

“…The pore structures of these polymers are formed by the accumulation of small particles, corresponding with SEM images. [27,28] On one hand, the pore structures of CP1-CP7 also verified porphyrin polymerization, due to different interaction between metal ion and H 2 TZP. On the other hand, the pore structures enhanced the surface area of the polymers that also enhanced the reactive sites on the surface of porphyrin polymers during the reaction.…”