2003
DOI: 10.1135/cccc20031745
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Abstract: In the last fifteen years, a large variety of specialty polymers of diverse chemical structure and functionality have been synthesized with the rhodium-based catalysts. The high tolerance to the reaction medium and functional groups of monomers, as well as ability to control various structure features of the polymer formed are typical properties of these catalysts. In addition, some rhodium catalysts can be anchored to inorganic or organic supports or dissolved in ionic liquids to form heterophase polymerizati… Show more

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Cited by 97 publications
(66 citation statements)
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References 179 publications
(189 reference statements)
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“…A pioneering work was done by Kern as early as the 1960s, 57 in which monomer 1 was polymerized with RhCl 3 -LiBH 4 and (Ph 3 P) 3 RhCl. The selective formation of cis-transoidal structure was confirmed by Furlani and Feast using 1 H and 13 C NMR, 58 and it was found by Tabata that Et 3 N works as an effective cocatalyst in the [(nbd)RhCl] 2 -catalyzed (nbd: 2,5-norbornadiene) polymerization. 59 The features of Rh catalysts as compared with group 5 and 6 metathesis catalysts include cis-transoidal structure of the formed polymer, tolerance to polar moieties in the monomer and to polar solvents, and restriction of the kinds of monomers to monosubstituted acetylenes.…”
Section: Rh Catalystsmentioning
confidence: 86%
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“…A pioneering work was done by Kern as early as the 1960s, 57 in which monomer 1 was polymerized with RhCl 3 -LiBH 4 and (Ph 3 P) 3 RhCl. The selective formation of cis-transoidal structure was confirmed by Furlani and Feast using 1 H and 13 C NMR, 58 and it was found by Tabata that Et 3 N works as an effective cocatalyst in the [(nbd)RhCl] 2 -catalyzed (nbd: 2,5-norbornadiene) polymerization. 59 The features of Rh catalysts as compared with group 5 and 6 metathesis catalysts include cis-transoidal structure of the formed polymer, tolerance to polar moieties in the monomer and to polar solvents, and restriction of the kinds of monomers to monosubstituted acetylenes.…”
Section: Rh Catalystsmentioning
confidence: 86%
“…However, there was no convincing evidence at that time. In 1980 Katz reported that Fischer and Casey carbenes polymerize substituted acetylenes, 42 and further he analyzed the partly deuterated poly(1) by using 13 C NMR nutation technique to conclude that the Mo-catalyzed polymerization proceeds by the metathesis mechanism. 43 If the polymerization of substituted acetylenes by group 5 and 6 transition metal catalysts proceeds through the metathesis mechanism, suitable olefins should serve as chain transfer agents.…”
Section: Metathesis Mechanismmentioning
confidence: 99%
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