2015
DOI: 10.1002/pola.27765
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Abstract: Controlled radical polymerizations have significantly impacted the field of polymer science by facilitating the synthesis of polymers with greater control over molecular weight, structure, and dispersity (Ð). As these synthetic techniques continue to evolve, more degrees of control can be realized via external regulation. Recent work has demonstrated external regulation of a controlled radical polymerization process with light using a photoredox Ir‐catalyst. While light offers many advantages as a stimulus for… Show more

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Cited by 79 publications
(67 citation statements)
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“…Halar tubing was used for the flow reactor based on studies optimizing a continuous flow reactor system using photo-induced ATRP catalyzed by fac -Ir(ppy) 3 . 44 …”
Section: Methodsmentioning
confidence: 99%
“…Halar tubing was used for the flow reactor based on studies optimizing a continuous flow reactor system using photo-induced ATRP catalyzed by fac -Ir(ppy) 3 . 44 …”
Section: Methodsmentioning
confidence: 99%
“…In the latter case, in addition to the high performances of Ir III ‐based CRP under soft conditions, the authors noticed that key parameters such as the light intensity, the irradiation source, the Ir III concentration, and residual compounds affected the CRP results . Finally, the Ir III photoinduced CRP methodology was expanded to the production of poly(MMA) in continuous‐flow microreactors under light irradiation …”
Section: Photocatalysts (Pcs) In Controlled Radical Photopolymerizatmentioning
confidence: 99%
“…To polymerize the new diTBA monomer, our attention was directed to recent advances in photo‐induced controlled radical polymerization . A recent report by Haddleton and coworkers demonstrated that tert ‐butyl acrylate could be polymerized to very high conversions while retaining excellent end group fidelity (>99%) using catalytic Cu II Br 2 and an aliphatic amine ligand, Me 6 ‐Tren, in the presence of UV ( λ max ≈ 360nm) light .…”
Section: Resultsmentioning
confidence: 99%