ABSTRACT:The present work investigates the relationship between whole-rock geochemistry and stable isotope composition from carbonatites belonging to the Tapira, Araxá, Salitre, Serra Negra, Catalão I, and Catalão II alkaline-carbonatite complexes of the Alto Paranaiba Igneous Province (APIP), central Brazil and from the Jacupiranga Complex, of the Ponta Grossa Province, southeast Brazil. The APIP complexes are ultrapotassic, comprising bebedourites, phoscorites, nelsonites, and carbonatites, whereas Jacupiranga is a sodic complex composed of ijolite-series rocks, syenites, carbonatites, and alkaline gabbros. The geochemistry data allied to mineralogical constraints allowed us to classify the carbonatites into five groups, and to devise a chemical index (BaO/(BaO+SrO)) to gauge the magmatic evolution of the studied carbonatites.The APIP carbonatites evolve from apatite-rich calciocarbonatites toward Ba-, Sr-, and rare earth element (REE)-rich magnesiocarbonatites. This evolution is mostly driven by apatite, phlogopite, dolomite, and calcite fractionation and consequent enrichment in monazite, norsethite, and strontianite. Stable isotope data show a wide diversity of petrogenetic processes in play at the APIP, relatively to the Jacupiranga Complex, which is interpreted as a result of the shallower intrusion levels of the APIP complexes. Such shallower emplacement, at low lithostatic pressure, allowed for a complex interplay of fractional crystallization, liquid immiscibility, degassing, and interaction with hydrothermal and carbohydrothermal systems.
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INTRODUCTIONBrazilian alkaline provinces have been studied by a range of techniques such as whole-rock geochemistry, mineral chemistry, stable and radiogenic isotope geochemistry, with a range of petrogenetic aplications (Gomide et al. 2013, Barbosa 2009, Cordeiro et al. 2011, Grasso 2010, Ribeiro 2008, CominChiaramonti et al. 2001, Traversa 2001, Andrade et al. 2002, Huang et al. 1995, Santos & Clayton 1995, Ulbrich & Gomes 1981. We aim to contribute to the knowledge of carbonatite petrogenetic evolution, investigating the relationships between whole-rock geochemistry and stable isotope geochemistry data, reporting geochemical and isotopic data from carbonatites of the Late-Cretaceous Alto Paranaíba Igneous Province (APIP), and discuss their implications for magma evolution, both at single-complex and Province-wide scales. The results obtained are compared with the Early-Cretaceous Jacupiranga carbonatite complex, in the Ponta Grossa Province.Alkaline rocks and alkaline-carbonatite associations include highly variable petrographic types and correspondingly extensive nomenclature. We adopt the nomenclature proposed by Le Maitre et al. The APIP alkaline-carbonatite complexes are multistage intrusions formed by rocks derived from the bebedourite, carbonatite, and phoscorite series, which are related to each other by a complex interplay of fractional crystallization, liquid immiscibility, and degassing (Brod et al. 2004, Ribeiro 2008, Barbosa 2009, Cordeir...