DOI: 10.1002/oms.1210090108
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Abstract: The mass spectrometric study of 2,4-dinitrophenyl 2'-R-phenyl ethers (R = H, Me, Et, i-Pr, tert-Bu) showed that (1) fragmentation proceeds differently from unsubstituted and 4-nitrosubstituted diphenyl ethers; (2) important fragmentation routes involve interannular migrations and cyclizations; (3) these occur between two groups ortho to the ether linkage while the ethers are in unfavorable endo, end0 twist conformations ; (4) the observed interannular interactions can be ustitied by the existence in these co… Show more

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