Abstract:Cation exchange is one of the most important classes of reactions controlling the soil solution composition for major ions. Modeling ion-exchange equilibria is complicated by ternary solid-phase interactions. The present study alleges that spurious ternary-interactions can be reported when dilution of the exchanging ions by other ions on the solid-phase is not accounted for in models. Ion-exchange equilibria data from the NH 4 + -Ca 2+ -K + -vermiculite system is used to demonstrate that previous reports of te… Show more
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