“…X-ray photoelectron spectroscopy (XPS) measurements evidence the existence of Te, B, Al, Zn, O, Na, Cs, Pb, and Br signals, and the slight shift of Cs, Pb, and Br peaks toward larger binding energy after glass crystallization probably attributes to the modification of ligand fields surrounding these elements (Figure S3). Fourier transform infrared (FTIR) spectra (Figure S4) confirm that glass network structure mainly consists of [TeO 4 ], [BO 4 ], and [BO 3 ] units, where the related stretching vibrations of Te–O and B–O bonds are clearly observed. , As a supplement, Raman spectra of PG and QDs@glass samples were recorded to trace the structural variation after glass crystallization. As shown in Figure b, both PG and GC exhibit similar strong peaks at 753, 670, and 472 cm –1 assigned to stretching vibration of TeO 4 trigonal bipyramid and stretching and bending vibrations of Te–O–Te group.…”