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Cited by 112 publications
(35 citation statements)
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“…The most characteristic part of the chromium(III) spectrum is the two d-d transitions observable in the 350-650 nm region [32]. Our k max values are in good agreement with the literature values [28,29]. These results indicate that EDTA coordinates with the chromium(III) species.…”
Section: Product Identificationsupporting
confidence: 92%
See 1 more Smart Citation
“…The most characteristic part of the chromium(III) spectrum is the two d-d transitions observable in the 350-650 nm region [32]. Our k max values are in good agreement with the literature values [28,29]. These results indicate that EDTA coordinates with the chromium(III) species.…”
Section: Product Identificationsupporting
confidence: 92%
“…It is well known that the spectra of K 2 Cr 2 O 7 and the chromium(III)-EDTA complex solution possess a shoulder located at 425 nm [27] ( Figure 1A) and two bands with k max ¼ 410 and 550 nm [28] (Figure 1C), respectively. It is observed that the spectrum of K 2 Cr 2 O 7 changes upon the addition of a mixture of EDTA and manganese(II) solutions.…”
Section: Product Identificationmentioning
confidence: 97%
“…The calculated value of K 2 in this study seems to be more reasonable than the calculated value (2.3 9 10 -7 mol dm -3 ) reported in the previous study. The value K 2 calculated here compares fairly well with value obtained for the deprotonation of [Cr III (EDTA)(H 2 O)] -(3 9 10 -8 mo1 dm -3 ) [18]. The deprotonation constant of the Co(II) is expected to be lower than that of the Cr(III) considering the charges on the two metal ions.…”
Section: Resultssupporting
confidence: 62%
“…Therefore the [Cr III EDTA(H 2 O)] − complex has been chosen as a model system. Moreover, the complex is substitutionally labile and can be easily modified by exchange the weakly bonded water molecule to the selected ligand L, or even EDTA itself [37][38][39][40][41][42][43][44][45][46][47], what makes the system easy to manipulate.…”
Section: Cr(iii) Photoredox Pathwaymentioning
confidence: 99%
“…was prepared from chromium(III) nitrate and disodium salt of ethylenediaminetetraacetic acid according to the method previously reported [47]. Its purity was checked by UV-VIS spectroscopy.…”
Section: Materials and Procedures Na[credta(h 2 O)]mentioning
confidence: 99%