Journal of Chromatography A 2012 DOI: 10.1016/j.chroma.2012.01.084 View full text
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Ketevan Lomsadze, George Jibuti, Tivadar Farkas, Bezhan Chankvetadze

Abstract: This article reports comparative high-performance liquid chromatographic separations of enantiomers with chiral stationary phases (CSPs) prepared by coating cellulose tris(4-chloro-3-methylphenylcarbamate) on totally porous and on core-shell type silica of comparable particle diameter. Several interesting observations were made: (1) the selectivity of separation was higher on core-shell type CSP compared to totally porous CSP at comparable content of chiral selector (polysaccharide derivative); (2) much flatte…

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