volume 49, issue 40, P7166-7168 2010
DOI: 10.1002/anie.201003133
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Abstract: ,3-dienes · enantioselectivity · homogeneous catalysis · hydrovinylationThe transition-metal-catalyzed codimerization of 1,3-dienes with alkenes, also called hydrovinylation, offers great potential for practical synthetic applications. The hydrovinylation reaction was first reported by Alderson et al. [1] in 1965. They used rhodium and ruthenium salts under high ethene pressure with a range of substrates. Since then, a number of other metals such as iron, cobalt, nickel, and palladium have been used.[2] Most…

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