We address the homotopy theory of 2-crossed modules of commutative algebras. In particular, we define the concept of a 2-fold homotopy between a pair of 1-fold homotopies connecting 2-crossed module maps A → A ′ . We also prove that if the domain 2-crossed module A is free up to order one (i.e. if the bottom algebra is a polynomial algebra) then we have a 2-groupoid of 2-crossed module maps A → A ′ and their homotopies and 2-fold homotopies. is what is called a pre-crossed module. The second Peiffer relation does not hold in general. However we have a map {, } : E × E → L, called the Peiffer lifting, measuring how far Peiffer 2 is from being satisfied, namely:The category of 2-crossed modules is equivalent to a reflexive subcategory of the category of simplicial groups [11,23,24]. Thus [10,19] an adjunction:exists. Such is constructed in the obvious way from the Dwyer-Kan loop-group G ⊣ W adjunction between the category of simplicial sets and the category of simplicial groups; [14,16,26]. B is the simplicial classifying space functor [7] and Π 3 was explicitly constructed in [15] from triad homotopy groups of the geometric realisation. We thus [9,16] have a model category structure in the category of 2-crossed modules of groups in which all objects are fibrant and which renders a 2-crossed module A = (L → E → G, ◮, {, }) cofibrant if, and only if, it is a retract of a totally free 2-crossed module, the latter meaning that G is a free group and that (∂ : E → G, ◮) is a free pre-crossed module [15,19,23,24].Following previous constructions in the context of quadratic modules (a particular case of 2crossed modules) [7] and Gray categories [12], a homotopy relation between group 2-crossed module maps was addressed in [18,19], via path-objects, and proven in [15] to faithfully model homotopy classes of maps between 3-types. Given 2-crossed modules A and B, of groups, if A is totally free (therefore cofibrant), if follows that homotopy between maps A → B is an equivalence relation. A surprising result of [18,19] was that, in order for homotopy between maps A → B to be an equivalence relation, we solely need to impose that A is free up to order one, meaning that G is a free group. Moreover in the latter case we can define, if we are given a free basis of G, a 2-groupoid of maps A → B, homotopies between maps, and 2-fold homotopies between homotopies.This paper, which is a follow-up of [1], contains a proof that the latter property (1-freeness suffices to compose homotopies and 2-fold homotopies) also holds for 2-crossed modules of commutative algebras.All algebras in this paper will be commutative and over a fixed ring κ, not necessarily with 1. Crossed modules and 2-crossed modules of algebras [4,5,6,13,25] are defined in the same way as in the group case, essentially switching actions by automorphisms to actions by multipliers, where a multiplier in an algebra R is a linear map f : R → R such that f (ab) = f (a)b, for each a, b ∈ R. A 2-crossed module of algebras A = (L ∂2 −→ E ∂1 −→ R, ◮, {, }) has an underlying comp...