1990
DOI: 10.1139/v90-007
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Abstract: M A R~A PIEDAD ALVAREZ-MACHO and M A R~A ISABEL MONTEQUI-MARTIN. Can. J. Chern. 68,29 (1990). The oxidation of lactlc acid by chromic acid was studied at high concentrations of HCIO?, HN03, and H2S04 It was observed that the reaction rate depends not only on the acidity of the medium, but also on the nature of the mineral acid. The use of the Bunnett and Bunnett-Olsen criteria and the excess acidity concept allows us to propose a reaction mechanism of the A-2 type, the rate-determining step being a bimolecular… Show more

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Cited by 5 publications
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“…Chromate Ester Formation. Formation of a chromate ester has been well-established in the Cr(VI) oxidation of alcohols [36][37][38][39][40] and aldehydes [41][42][43][44]. Analogous Cr(VI)thiol esters have been observed in Cr(VI) oxidations of compounds with sulfhydryl moieties [45][46][47][48][49][50].…”
Section: Discussionmentioning
confidence: 99%
“…Chromate Ester Formation. Formation of a chromate ester has been well-established in the Cr(VI) oxidation of alcohols [36][37][38][39][40] and aldehydes [41][42][43][44]. Analogous Cr(VI)thiol esters have been observed in Cr(VI) oxidations of compounds with sulfhydryl moieties [45][46][47][48][49][50].…”
Section: Discussionmentioning
confidence: 99%