Topological insulators (TI's) are a new class of quantum matter with extraordinary surface electronic states, which bear great potential for spintronics and error-tolerant quantum computing. In order to put a TI into any practical use, these materials need to be fabricated into devices whose basic units are often p-n junctions. Unique electronic properties of a 'topological' p-n junction were proposed theoretically such as the junction electronic state and the spin rectification. However, the fabrication of a lateral topological p-n junction has been challenging because of materials, process, and fundamental reasons. Here, we demonstrate an innovative approach to realize a p-n junction of topological surface states (TSS's) of a three-dimensional (3D) topological insulator (TI) with an atomically abrupt interface. When a ultrathin Sb film is grown on a 3D TI of Bi 2 Se 3 with a typical n-type TSS, the surface develops a strongly p-type TSS through the substantial hybridization between the 2D Sb film and the Bi 2 Se 3 surface. Thus, the Bi 2 Se 3 surface covered partially with Sb films bifurcates into areas of n-and p-type TSS's as separated by atomic step edges with a lateral electronic junction of as short as 2 nm. This approach opens a different avenue toward various electronic and spintronic devices based on well defined topological p-n junctions with the scalability down to atomic dimensions.Keywords topological insulator, topological p-n junction, angle-resolved photoemission spectroscopy, scanning tunneling microscopy/spectroscopy, ultrathin Sb film Surface states of topological insulators, 1,2 called topological surface states (TSS's), are robustly protected by the bulk topological nature and form necessarily a Dirac band with their spins locked helically with momentum. 1-6 These unique properties find obvious merits in spintronic applications and can yield a Majorana Fermion in proximity with supercon-2 ductivity. 7,8 However, there has been a huge barrier in making devices based on TSS's. The challenge is closely related to the notorious issue of controlling impurities or dopants in a TI crystal. While quite a few works tried to control the chemical potential of a TSS by impurity doping, 4,9-14 the deterioration of the surface channel and the inclusion of bulk channels were inevitable in many cases. Especially, the tunability of the chemical potential was often not enough to make a good p-type TSS. Fabricating a well defined topological p-n junction is even more challenging, 15-18 which represents one of the most important technological issues in staging applications of TI's. Nevertheless, a topological p-n junction, defined as an electronic junction of a p-and a n-type TSS, features unique properties, which are not shared by conventional p-n junctions of semiconductors but promise attractive new applications. 7,8 At a topological p-n junction, the electron scattering and transport are largely governed by the spin polarization of TSS's involved. This property provides the spin rectification eff...