volume 2019, issue 41, P4405-4411 2019
DOI: 10.1002/ejic.201900765
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Abstract: Enantiopure Δ and Λ forms of the spin crossover Mn 3+ chelate complex [Mn{5-OCF 3 -sal 2 (323)}] + were prepared by co-crystallization with the (R,R) and (S,S) forms of the chiral spiroborate anion bis[1,1′-binaphthyl-2,2′-diolato]boron. The absolute structures of the enantiomers were established by X-ray crystallography at 100 K and at 293 K. The enantiomeric [a]