ChemInform Abstract: The First Total Synthesis of Cytopiloyne, an Antidiabetic Polyacetylenic Glucoside.

Abstract

The First Total Synthesis of Cytopiloyne, an Antidiabetic Polyacetylenic Glucoside. -Both diastereomers are prepared and their structures are characterized. Comparison of the new data with those in the literature confirm that the (2R)-diastereomer (I) is the natural product. -(KUMAR, C. R.; TSAI, C.-H.; CHAO, Y.-S.; LEE*, J.-C.; Chem. Eur. J. 17 (2011) 31, 8696-8703, http://dx.