volume 30, issue 44, Pno-no 2010
DOI: 10.1002/chin.199944036
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Yoshiro Masuyama, Takanori Ito, Kentaro Tachi et al.

Abstract: 1999 stereochemistry stereochemistry (general, optical resolution) O 0030 -036syn-Diastereoselective Carbonyl Allylation by 1-or 3-Substituted Prop-2-en-1-ols with Tin(II) Iodide and Tetrabutylammonium Iodide.-Efficient allylation of benzaldehydes is achieved in the presence of SnI 2 and catalytic amounts of Bu 4 NI. Allylations of benzaldehydes by (E)-allylic alcohols bearing an aliphatic group at the α-or γ-position [cf. (IV)] proceed syn-diastereoselectively in contrast to related Pd-catalyzed allylations …

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