1987
DOI: 10.1002/chin.198715136
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T. NEGORO,
Y. IKEDA

Abstract: Abstract 136 ChemInform 1987, 18, No. 15, Abstract 136 ChemInform Abstract The bromochlorination of the acetylenes (I) using the reagents (IV) or (VIII) can occur in a regiospecific or non-regiospecific as well as in a stereospecific or non-stereospecific manner. The Markownikoff (II) and anti-Markownikoff (III) products are obtained from (Ia)-(Ic) with (IV) or from (Ib), (Ic) with (VIII). (Id) yields the analogue (V) of (II) together with the acetylene (VI). The E/Z isomers (IIa), (V) + (VII) are forme…

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