volume 30, issue 43, Pno-no 2010
DOI: 10.1002/chin.199943037
View full text
|
|
Share
Albert Levai, Tamas Patonay

Abstract: Reaction of E-2-Arylidene-1-indanones, Z-Aurones, Z-1-Thioaurones and Z-2-Arylidene-2,3-dihydro-1H-indole-3-ones with Diazomethane.-The 1,3-dipolar cycloaddition of arylidene indanones and aurones (I) respectively affords trans-spiro-1-pyrazolines (III) as sole products. However the same reaction with arylidene thioaurones and -dihydroindolones yields trans cyclopropanes (V) as a result of the spontaneous denitrogenation of the initially formed pyrazolines. -(LEVAI, ALBERT; PATONAY, TAMAS; J. Heterocycl. Chem…

expand abstract