ChemInform Abstract: NITROGEN‐ OR CARBON‐GOLD DERIVATIVES OF AZOLES

Bonati, Federica Cester; Burini, Alfredo; Felici, M.; Pietroni, Bianca Rosa

doi:10.1002/chin.198338327

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1985

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“…Our investigations in the field of gold chemistry have been concerned with the interaction between Au(I) and several nitrogen-containing heterocycles such as pyrazoles [3], pyrazolones [4], indazoles, imidazoles [5], triazoles, tetrazole [6], or pyridones [7]. Isolation and characterization of several N-and of a few C-(trisubstituted phosphine)gold(I) deriva tives of the said molecules was reported.…”

Section: Introductionmentioning

confidence: 99%

Mono- and Binuclear Gold(I) Compounds Containing Deprotonated Purines and Pyrimidines

Bonati

Burini

Pietroni

1985

Zeitschrift Für Naturforschung B

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Abstract In the presence of alkali and LAuCl one or two -NH - groups of a purine or pyrimidine base can be transformed into - N(AuL)- groups giving stable and soluble compounds containing one or two two-coordinated gold(I) nuclei; mononuclear LAu - Q' or binuclear LAu - Q - AuL with a monodentate Q'- or an exobidentate O-- ligand, resp. (Q'H = adenine, guanine, theobromine, theophylline, azaguanine or cytosine; QH2 - thymine or uracyl; L = triphenylphosphine)

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