ChemInform Abstract: New Organocatalysts for the Asymmetric Reduction of Imines with Trichlorosilane.

Malkov, Andrei V.; Vranková, Kvetoslava; Sigerson, Ralph C.; Stončius, Sigitas; Kočovský, Pavel

doi:10.1002/chin.201010068

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2017

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“…An organic Lewis base/HSiCl 3 system has proven to be a powerful combination for the reduction of C=N, C=O and C=C bonds by us and others. [17][18][19][20][21][22][23][24][25] In 2011, we developed the first organic Lewis base/HSiCl 3 system for the asymmetric hydrosilylation of 2,3-disubstituted indoles affording high stereoselectivities and good substrate generality (Scheme 1). 17 We also developed the first organic Lewis base catalyzed tandem approach to get chiral 2,3-disubstituted indolines from indoles and aldehydes.…”

Section: = H Mementioning

confidence: 99%