volume 30, issue 43, Pno-no 2010
DOI: 10.1002/chin.199943054
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Herbert C. Brown,
Guang-Ming Chen,
Michael P. Jennings
et al.

Abstract: -054Markovnikov Hydroboration of Perfluoroalkylethylenes.-The hydroboration of various perfluoroalkenes and perfluorostyrene (I) with BHX 2 reagents (X: Cl, Br) proceeds with excellent regioselectivity to furnish, after oxidation, secondary alcohols (Markovnikov adducts) in good yields. With other hydroboration reagents a lower selectivity (e.g. with BH 3 ·THF) or a very slow reaction (e.g. with 9-BBN or catecholborane) are observed. -(BROWN, HERBERT C.; CHEN, GUANG-MING; JENNINGS, MICHAEL P.; RAMACHANDRAN, P…

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