1987
DOI: 10.1002/chin.198713087
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A. R. KATRITZKY,
B. BRYCKI

Abstract: Abstract 087ChemInform Abstract The rates of solvolysis of (I) are almost independent of solvent and show less variation with the substrate structure than do analogues with leaving groups departing as anions. No evidence is found for any nucleophilic assistance by solvents. In contrast, the dependence on solvent polarity of previously measured solvolysis rates for (II) and (III) with deviations from straight lines for acetic acid and pentanol shows nucleophilic assistance in the latter two solvents only for t…

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