1987
DOI: 10.1002/chin.198715005
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S. SUEZER,
L. ANDREWS

Abstract: Abstract 005ChemInform Abstract As shown by matrix IR studies alkali metal atoms interact with NH3 in solid Ar to form 1:1 molecular complexes. This behavior is in contrast to the well known ionic solutions in liquid NH3. The smaller alkali metal atoms Li and Na appear to act as weak Lewis acids while the increased ammonia interaction with K and Cs may suggest a possible acid-base role reversal for the heavier alkali metal complexes. At higher metal-ammonia doping concentrations higher aggregate bands of (M)n…

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