volume 30, issue 43, Pno-no 2010
DOI: 10.1002/chin.199943095
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Jordan M. Cummins,
Ulf-H. Dolling,
Alan W. Douglas
et al.

Abstract: Intramolecular Aromatic 1,5-Hydrogen Transfer in Free RadicalReactions. Part 2. Rearrangement of Iodobenzophenones.-Main or exclusive reaction of the title compounds (I) under irradiation is the rearrangement to isomers of type (II). Photolysis of (Ib)-(Id) in solvents corresponding to R (benzene, thiophene, etc.) gives mixtures of (I) and (II) whose ratio depends on the nature of the aromatic substituent. Reaction of the diphenyl ether (VII) gives a mixture of the cyclization and the substitution product; ri…

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