ChemInform Abstract: Fivefold‐Diamond Structure of Adamantane‐1,3,5,7‐tetracarboxylic Acid

Ermer, Otto

doi:10.1002/chin.198839059

Cited by 3 publications

(3 citation statements)

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“…Subsequently, other compounds based on linking metal ions with ADC 26 , ETC 27 , INT 28 , BPY 29,30 and BPCN 31 have been reported. Tetrahedral building blocks such as HMT 32 and MCP 33 have been linked by metal ions to form decorated diamond structures, while TPY 34 and ATC 35 are examples of links predesigned so that their assembly into diamond networks is done by linking through hydrogen bonding.…”

Section: Perspectives and Challengesmentioning

confidence: 99%

Reticular synthesis and the design of new materials

Yaghi

O’Keeffe

Ockwig

et al. 2003

Nature

8,841

4,998

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The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal-oxygen-carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.

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Section: Perspectives and Challengesmentioning

confidence: 99%

Reticular synthesis and the design of new materials

Yaghi

O’Keeffe

Ockwig

et al. 2003

Nature

8,841

4,998

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“…The strategy uses preformed molecular modules that are designed to be connectable in specific ways. The origin of the approach can be traced to two parallel advances in organic and inorganic chemistry 14 , one showing that predictably ordered networks can be built from modules that engage in directional noncovalent interactions such as hydrogen bonds 15 – 18 , and the other demonstrating that coordinative bonds to metals can also be used to control construction 19 . When modules are devised to be poorly flexible and to hold their neighbors in particular positions, the resulting materials cannot usually achieve effective packing and optimal intermolecular bonding at the same time.…”

Section: Modular Construction Of a New Generation Of Porous Ordered Mmentioning

confidence: 99%

Atoms and the void: modular construction of ordered porous solids

Wuest

2020

Nat Commun

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For millennia, humans have exploited the special properties of porous materials. Advances in recent years have yielded a new generation of finely structured porous materials that allow processes to be controlled at the molecular level. These materials are built by a strategy of modular construction, using molecular components designed to position their neighbors in ways that create predictable voids.

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“…Adamantane has been recognized for a long time as an important molecule for crystal design. An example of exploiting the potential of the adamantane moiety is 1,3,5,7-tetrakis(1,2,4-triazol-4-yl)adamantane [1], but even more simple 1,3,5,7-adamantanetetracarboxylic acid can produce spectacular frameworks [2]. A number of different adamantane derivatives have been designed and their coordination ability explored [3,4,5,6,7,8,9,10,11,12,13,14].…”

Section: Introductionmentioning

confidence: 99%

Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers

et al. 2019

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For the first time, orthogonally substituted azole-carboxylate adamantane ligands were synthesized and used for preparation of coordination polymers. The angle-shaped ligands were prepared by the reaction of 1-adamantanecarboxylic acid and azoles (1H-1,2,4-triazole, 3-methyl-1H-1,2,4-triazole, 3,5-dimethyl-1H-1,2,4-triazole, 1H-tetrazole, 5-methyl-1H-tetrazole) in concentrated sulfuric acid. Variation of the solvent and substituents in azole rings allowed to prepare both 1D and 2D copper(II) and nickel(II) coordination polymers, [Cu2(trzadc)4(H2O)0.7]∙DMF∙0.3H2O, [Cu(trzadc)2(MeOH)]∙MeOH, [Ni(trzadc)2(MeOH)2] and [Cu2(mtrzadc)3(MeOH)]+NO3– (trzadc-3-(1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid; mtrzadc-3-(3-methyl-1,2,4-triazol-1-yl)-adamantane-1-carboxylic acid) which were structurally characterized by single crystal X-ray diffraction. Complex [Cu(trzadc)2(MeOH)]∙MeOH was shown to act as a catalyst in the Chan-Evans-Lam arylation reaction.

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ChemInform Abstract: Fivefold‐Diamond Structure of Adamantane‐1,3,5,7‐tetracarboxylic Acid

Abstract: ChemInform Abstract (space group I41/a with Z=4).

Cited by 3 publications

References 1 publication

Reticular synthesis and the design of new materials

Reticular synthesis and the design of new materials

Atoms and the void: modular construction of ordered porous solids

Facile Synthesis of 3-(Azol-1-yl)-1-adamantanecarboxylic Acids—New Bifunctional Angle-Shaped Building Blocks for Coordination Polymers

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