volume 30, issue 43, Pno-no 2010
DOI: 10.1002/chin.199943010
View full text
|
|
Share
P. Millet, J. Galy, M. Johnsson

Abstract: structure structure (solids and liquids) D 2000 -010Crystal Growth and Structure of V 2 V Se 2 IV O 9 ; Comparison with V 2 Te 2 O 9 .-Single crystals of the title compound are obtained as a side product during a study of the CuCl 2 -V 2 O 5 -SeO 2 system. The three components V 2 O 5 , CuCl 2 , and SeO 2 are reacted in 1:2:1 molar ratio at 350 • C (evacuated glass tube, 260 h). V 2 Se 2 O 9 crystallizes in the monoclinic space group P2 1 /n with Z = 4. The structure is built up by strongly distorted VO 6 oct…

expand abstract