1997
DOI: 10.1002/(sici)1099-0801(199703)11:2<117::aid-bmc669>3.0.co;2-v
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Chemiluminescence Determination of Tiopronin by Flow Injection Analysis Based on Cerium(IV) Oxidation Sensitized by Quinine
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1997
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Cited by 10 publications
(5 citation statements)
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“…The reduction of Ce(IV) produces excited Ce(III), which is deactivated by emitting light of 350 nm, yielding a weak CL signal. 28–32 Quinine is a good fluorescent substance (Φ = 0.577), having an emission maximum at about 450 nm. 33 Excited Ce(III) transfers energy to the quinine, yielding excited quinine, which is responsible for the strong CL observed.…”
Section: Resultsmentioning
confidence: 99%
“…The reduction of Ce(IV) produces excited Ce(III), which is deactivated by emitting light of 350 nm, yielding a weak CL signal. 28–32 Quinine is a good fluorescent substance (Φ = 0.577), having an emission maximum at about 450 nm. 33 Excited Ce(III) transfers energy to the quinine, yielding excited quinine, which is responsible for the strong CL observed.…”
Section: Resultsmentioning
confidence: 99%
“…A quinine is a sensitizer of the reaction of thiolcontaining drugs with cerium(IV) in sulphuric acid medium [29][30][31]. Quinine is a good fluorescent substance (φ = 0.577), having an emission maximum at about 450 nm [63].…”
Section: The Other Ce(iv) -Sensitiser Systemsmentioning
confidence: 99%
“…Cerium (III), which is formed by the reduction of cerium(IV), is a well-known fluorescent ion, with the maximum emission at λ~355 nm [41][42][43] and therefore, it is a possible CL emitter. Excited sulphur dioxide species (SO 2 *) emit weak light at 300-450 nm [44,45], therefore the compounds showing strong fluorescence, such as rhodamine B [28,46], quinine [29][30][31] or lanthanide ions [32] are introduced to many reaction systems containing Ce(IV) ions. However, the CL intensity is very weak due to the low luminescence efficiency of SO 2 * .…”
Section: Reaction Conditions and Species Emitted From CL Reaction Sysmentioning
confidence: 99%
“…QN, among its other uses, has been employed as a sensitizing agent due to its exceptional quantum fluorescence efficiency in acidic media [9]. QN has been utilized for the development of many chemiluminescence methods [10] with different oxidants such as cerium(IV) [11], diperiodatonickelate(IV) [12], potassium bromate [13], and permanganate [14].…”
Section: Introductionmentioning
confidence: 99%
