volume 9, issue 9, P2523-2540 1971
DOI: 10.1002/pol.1971.150090909
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Abstract: synopsisA self-consistent set of chemical thermodynamic values for the polymerization of formaldehyde in the gas phase and in aqueous solution is obtained with the aid of recent experimental thermochemical results and the use of selected methods of calculation of data not otherwise available. Enthalpies, entropies, and Gibbs free energies of formation are derived for the various intermediates and products, including the first six hydroxyl-terminated oligomers. Simple equations for the logarithm of the equilib…

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