Chemical Composition of Hexene‐Based Linear Low‐Density Polyethylene by Infrared Spectroscopy and Chemometrics

Abstract

Mid and near infrared (MIR and NIR) spectroscopy associated with the partial least squares (PLS) method makes it possible to rapidly characterize the composition of linear low-density polyethylene (LLDPE) in a large range of 1-hexene content from 0 to 21 mol%. LLDPEs are produced using zirconocene catalysts activated with methylaluminoxane. PLS regression methods for MIR and NIR are constructed from this series of LLDPEs to quantify the 1-hexene content in unknown copolymers. In this case, the PLS regression method aims to correlate the 1-hexene content in the copolymers with their IR spectra. Multivariate calibration models are constructed by the PLS algorithm on pretreated data of MIR and NIR analyses. They are tested and validated by comparing results obtained by NMR and the PLS analyses for four unknown ethylene-1-hexene copolymers.

Synergistic effect of intumescent flame retardant and zinc borate on linear low‐density polyethylene

“…LLDPE has been developed rapidly and is now used in almost all the traditional PE markets. [2] However, LLDPE is a flammable material, and its LOI value is approximately 19.3%. During the combustion of LLDPE, melting and dripping will occur, a large amount of heat will be generated, and the flame will spread quickly, posing a high risk of casualties and property losses that limits the application of LLDPE in certain areas.…”