Electrostatic force detection with an atomic force microscope (AFM) is applied to the study of light-induced charge gratings on photorefractive materials. These gratings are generated by two crossed laser beams at a wavelength of 514 nm in Bi 12 SiO 20 and BaTiO 3 crystals. In contrast to conventional optical investigations of photorefractivity, where volume gratings of the refractive index are indirectly observed, the AFM allows a direct study of the charge gratings at the surface. Charge images of the two crystal materials are compared. The saturation of the charge gratings at increasing laser fluence is measured for both materials. From the observation of the phase shift between the light-intensity grating and the charge grating, the polarity of the charge carriers in Bi 12 SiO 20 is determined.The atomic force microscope (AFM) is by the far the most versatile instrument of the growing family of scanning probe microscopes. This is due to the multitude of different forces that can be studied with this instrument. In this paper, we present an application of the AFM to the measurement of electrostatic forces for the detection of light-induced charge distributions on photorefractive crystals.Photorefractive materials are of growing interest because of their applications in such fields as high-density optical data storage, real-time holography and optical phase conjugation, to name but a few. The photorefractive effect occurs in crystals that are both photoconducting and electro-optic [1]. In these materials, a spatially modulated light-intensity distribution, e.g. a light grating generated by the interference of two laser beams, is used to excite charge carriers. These carriers are redistributed by drift and diffusion until they are trapped to form a space-charge distribution. The accompanying electrostatic fields lead to a refractive-index pattern via the electro-optic effect. In the case of a grating, it is easily seen how this can be "read" by Bragg diffraction.In such an experiment, as in most of the conventional methods for investigating photorefractivity, the properties of the bulk of the material are studied. Increasingly, however, photorefractive materials are used as thin films, waveguides and optical fibers [2], and in these instances surface effects begin to be important. A surface-specific study of photorefractivity therefore becomes desirable. Electrostatic force microscopy, which allows the study of light-induced charge distributions at the surface of photorefractive materials, is ideal for this purpose. A sensitive method for charge detection on insulating surfaces was introduced by Terris et al. [3], and it was later applied by Schönenberger to image single electrons [4].A first demonstration of light-induced charge gratings on BaTiO 3 crystals was recently reported [5]. Here we present a detailed study of such gratings on Bi 12 SiO 20 (BSO) and on BaTiO 3 . A surface-specific microstructure in the charge images is revealed, and a saturation of the gratings at increasing light fluence was observed....