2008
DOI: 10.1111/j.1551-2916.2008.02553.x
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Cellular Ceramics by Direct Foaming of Emulsified Ceramic Powder Suspensions

Abstract: A new direct foaming method to produce macroporous cellular ceramics using surfactants as foam stabilizers is presented. The technology relies on the transition of a stabilized aqueous ceramic powder suspension containing a homogeneously dispersed alkane or air–alkane phase into cellular ceramics. The stabilization of the powder suspension and the emulsion is realized with particular emphasis on the interaction of both mechanisms providing enduring stability of the system up to high foaming degrees. Anionic, c… Show more

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Cited by 129 publications
(91 citation statements)
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“…The pore size, according to International Union of Pure and Applied Chemistry (IUPAC) 2 can be classified as micro (<2 nm), meso (2-50 nm) or macropores (>50 nm). The distribution and amount of pores determine specific properties, such as low density and thermal conductivity, high surface area, permeability and chemical and thermal stability 1,4,5 . Furthermore, glass foams have mechanical strength and chemical and thermal stabilities greater than the polymeric foams typically employed in such cases 1,6,7 .…”
Section: Introductionmentioning
confidence: 99%
“…The pore size, according to International Union of Pure and Applied Chemistry (IUPAC) 2 can be classified as micro (<2 nm), meso (2-50 nm) or macropores (>50 nm). The distribution and amount of pores determine specific properties, such as low density and thermal conductivity, high surface area, permeability and chemical and thermal stability 1,4,5 . Furthermore, glass foams have mechanical strength and chemical and thermal stabilities greater than the polymeric foams typically employed in such cases 1,6,7 .…”
Section: Introductionmentioning
confidence: 99%
“…10), 11) The key aspects in this process are the stabilization and consolidation mechanisms. However, the ceramic/binder foam is a thermodynamically unstable system in which heat treatment (drying, debinding) and gas bubble coarsening can lead to foam degradation and final destruction.…”
Section: Introductionmentioning
confidence: 99%
“…6 had adsorption achieved by ligand exchange, whereby a surface hydroxyl group is exchanged for another group. This occurred because of the Porous Ceramics http://dx.doi.org/10.5772/61047 63 favorable change in the surface charge by the removal of (OH 2 + ), a better leaving group, and replacement with (-OH) [44,45]. …”
mentioning
confidence: 99%