2020
DOI: 10.1002/cjce.23909
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Abstract: The complexity of composition of bio‐oil from biomass makes it difficult to produce upgraded bio‐oil via hydrodeoxygenation. In this paper, acetone is thus considered as a model compound of the ketones family abundant in pyrolysis bio‐oil. Results showed that high conversion rates of acetone between 86.6% and 91.9% were observed with the use of HZSM‐5, 5% Ni2P/HZSM‐5, and 10% Ni2P/HZSM‐5 catalysts. In most cases, CO2, C2H6, C3H6, and C3H8 were the dominant non‐condensable gas products. For liquid phase, the se… Show more

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Cited by 14 publications
(13 citation statements)
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“…Here, the support HZSM-5 was first grinded and sieved to 0.35-0.6 mm before loading the active phase. The specific preparation process and the characterization results of Ni 2 P/HZSM-5 catalysts by N 2 adsorption/desorption, ICP-OES elemental analysis, and XRD can be found in our previous work [27]. The acidity of the catalysts was characterized by FTIR spectroscopy (Spectrum BX, Perkin-Elmer) of adsorbed pyridine.…”
Section: Preparation Of the Catalystsmentioning
confidence: 99%
“…Here, the support HZSM-5 was first grinded and sieved to 0.35-0.6 mm before loading the active phase. The specific preparation process and the characterization results of Ni 2 P/HZSM-5 catalysts by N 2 adsorption/desorption, ICP-OES elemental analysis, and XRD can be found in our previous work [27]. The acidity of the catalysts was characterized by FTIR spectroscopy (Spectrum BX, Perkin-Elmer) of adsorbed pyridine.…”
Section: Preparation Of the Catalystsmentioning
confidence: 99%
“…The Ni 2 P/HZSM-5 catalysts were prepared by the incipient wetness impregnation method as a first step and temperature-programmed reduction (TPR) as the second step [30]. Here, the support HZSM-5 was first ground and sieved to 0.35-0.6 mm particle size before loading the active phase.…”
Section: Preparation and Characterization Of The Catalystsmentioning
confidence: 99%
“…Here, the support HZSM-5 was first ground and sieved to 0.35-0.6 mm particle size before loading the active phase. The specific preparation process and the characterization results of Ni 2 P/HZSM-5 catalysts by N 2 adsorption/desorption (BET surface), ICP-OES elemental analysis, and XRD can be found in our previous work [30]. In addition, the acidity of the catalysts was characterized by FT-IR (Spectrum BX, Perkin Elmer) at different pyridine desorption temperatures (100, 150, 275, and 400°C) after pyridine adsorption and could be found in the Supplementary materials (Figure S1).…”
Section: Preparation and Characterization Of The Catalystsmentioning
confidence: 99%
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“…Finally, optimal conditions gave a selectivity of 49% of aromatics (BTX: benzene, toluene, and xylene). [ 3 ]…”
mentioning
confidence: 99%