2018
DOI: 10.1002/ejic.201800326
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Abstract: This brief review is focused on recent advancements in methane catalytic oxidation, an important reaction for environmental remediation and clean power generation. Particular attention is given to Pd-based catalysts and novel strategies to gain a fundamental understanding of the reaction mechanism [a] 2885 hindered due to the high stability of the C-H bond (104 kcal mol -1 ). Nonetheless, in the presence of a catalyst, the apparent activation energy can be as low as 7-10 kcal mol -1 . As mentioned previously,… Show more

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Cited by 105 publications
(86 citation statements)
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“…Methane as the main component of natural gas is playing an increasingly important role in the global energy structure [1,2]. Effective catalytic complete oxidation of CH 4 can improve combustion efficiency and reduce air pollutants, such as CO, NO x , and unburned hydrocarbon [3][4][5][6][7][8]. It has therefore found great applications in modern industry, such as catalytic exhaust converters aimed to reduce methane emission and catalytic gas turbine combustors designed to combust fuel under mild conditions [9,10].…”
Section: Introductionmentioning
confidence: 99%
“…Methane as the main component of natural gas is playing an increasingly important role in the global energy structure [1,2]. Effective catalytic complete oxidation of CH 4 can improve combustion efficiency and reduce air pollutants, such as CO, NO x , and unburned hydrocarbon [3][4][5][6][7][8]. It has therefore found great applications in modern industry, such as catalytic exhaust converters aimed to reduce methane emission and catalytic gas turbine combustors designed to combust fuel under mild conditions [9,10].…”
Section: Introductionmentioning
confidence: 99%
“…It is not surprising that the quest for effective low‐temperature methane oxidation catalysts has focused mainly on systems involving precious metals, such as platinum and palladium . Metal oxide–supported PdO catalysts are generally considered to represent the state of the art for methane combustion catalysts . Recent research in this field has focused on improving activity at low temperatures, reducing the required loading of metal and improving the thermal and hydrothermal stability of PdO catalysts .…”
Section: Introductionmentioning
confidence: 99%
“…Thus, the removal of O 2 through reduction is a new, unique challenge for the capture of CO 2 . Of all metals, palladium (Pd) shows superior activity for catalyzing methane combustion in air at mild temperatures (≈400 °C) . Pd has been extensively studied but not used industrially due to its high cost.…”
Section: Introductionmentioning
confidence: 99%
“…Of all metals, palladium (Pd) shows superior activity for catalyzing methane combustion in air at mild temperatures (%400 C). [25,28] Pd has been extensively studied but not used industrially due to its high cost. For automobile emission remediation, Pd is used in catalytic converters to oxidize hydrocarbons.…”
Section: Introductionmentioning
confidence: 99%