Recycling
is a key component of the “Reduce, Reuse and Recycle”
waste hierarchy, and recycling of waste corrugated boards through
the reprocessing of them into new functional materials is of great
significance from the perspective of “waste to wealth”
and sustainability. Herein, high-performance carbonized waste corrugated
boards (CCB) reinforced with epoxy coating as lightweight structured
electromagnetic (EM) shields were demonstrated, and the resultant
CCB samples not only exhibited excellent shielding effectiveness (SE)
of ∼46.0–82.0 dB and ideal special SE value of ∼325–1171
dB/(g/cm3) related to their carbonization temperature or
different types at the frequency region of ∼8.2–12.4
GHz (X-band), but also showed superior thermal-insulation capability,
comparable to expanded polypropylene foam. Such shielding performance
should ascribe to their high electrical conductivity, as well as special
structure (sawtooth pattern sandwiched between two parallel surfaces),
capable of internal multiple reflections and constructive interference.
Moreover, the further construction of an ultrathin graphene skin-layer
on the CCB surfaces could reduce the carbonization temperature while
keeping their SE value, suggesting an effective and facile approach
for energy-saving.