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“…1) and is therefore difficult to discern in the indirect dimension of the 2D data. The exchange transfer occurs only between the diagonal components of the 2D multiplets,41 which results in the ‘tilted’ appearance of the cross‐peaks. One should add that the above‐mentioned cross‐peaks, originating from cross‐relaxation, and the exchange cross‐peaks (between free and bound chloroform) have opposite signs in the ROESY spectrum, as expected40 (this is not visible in the black‐and‐white figure).…”
Section: Resultsmentioning
confidence: 99%
“…1) and is therefore difficult to discern in the indirect dimension of the 2D data. The exchange transfer occurs only between the diagonal components of the 2D multiplets,41 which results in the ‘tilted’ appearance of the cross‐peaks. One should add that the above‐mentioned cross‐peaks, originating from cross‐relaxation, and the exchange cross‐peaks (between free and bound chloroform) have opposite signs in the ROESY spectrum, as expected40 (this is not visible in the black‐and‐white figure).…”
Section: Resultsmentioning
confidence: 99%