2002
DOI: 10.1177/0734242x0202000607
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Carbide sludge management in acetylene producing plants by using vacuum filtration

Abstract: Carbide sludge (10.4-11.5 tonnes day(-1)) is generated from the reaction of calcium carbide (900 kg) and water (6,000 L) in the production of acetylene (2,400 m3), in three selected acetylene manufacturing plants. The sludge (of pH 12.2 and containing Cu, Pb, Fe, Mn, Ni and Zn ions whose concentrations exceed the Department of Environment limits for industrial wastewater) was treated by vacuum filtration as a substitute for the ponding system, which is environmentally less acceptable. A similar system by flocc… Show more

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Cited by 33 publications
(12 citation statements)
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“…The remaining fraction of the calcium carbide is made up of 1-10% of calcium carbonate, 1-3% of carbon and silicates. Calcium carbide dissolves in water to produce calcium hydroxide and acetylene gas (C 2 H 2 ) [28][29][30] according to Eq. (2).…”
Section: Limingmentioning
confidence: 99%
“…The remaining fraction of the calcium carbide is made up of 1-10% of calcium carbonate, 1-3% of carbon and silicates. Calcium carbide dissolves in water to produce calcium hydroxide and acetylene gas (C 2 H 2 ) [28][29][30] according to Eq. (2).…”
Section: Limingmentioning
confidence: 99%
“…Calcium carbide (or calcium acetylide) and water are then reacted to produce acetylene and lime slurry (Reaction (2)) [1,2].…”
Section: Introductionmentioning
confidence: 99%
“…CLW, referred to as carbide lime sludge, hydrated lime waste, calcium hydroxide waste and other such designations, is generated as an aqueous slurry and is composed essentially by calcium hydroxide (Ca (OH) 2 % 85-95%) with minor parts of calcium carbonate (CaCO 3 % 1-10%), unreacted carbon and silicates (1-3%) [1,2,[4][5][6]. The characteristics of the sludge are influenced by processing parameters during acetylene fabrication [1]. Although not being classified as dangerous/hazardous, its managing and disposal require special caution.…”
Section: Introductionmentioning
confidence: 99%
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“…Lime and carbide lime (or lime sludge) can also provide the necessary alkali for activation. Carbide lime (CL) is a by-product of acetylene production through the hydrolysis of calcium carbide and composed essentially by calcium hydroxide with minor parts of calcium carbonate, unreacted carbon and silicates [7,8]. Accordingly, partially substituting for cement or lime, GGBS powder and carbide lime were used to modify the problematic silt in this study.…”
Section: Introductionmentioning
confidence: 99%