volume 106, issue 1, P99-106 1981
DOI: 10.1002/pssb.2221060112
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Abstract: A simple thermodynamical theory of crystal structure parameter calculation is suggested. Within the approximation of elastic atomic interaction formulae are obtained of the lattice parameter for different variants of cation distributions among non‐equivalent crystallographic positions in chemical compounds with spinel structure. The lattice parameter proved to be a function of two fundamental atomic characteristics: charge and bond length with an anion. The experimental and theoretical values are in good agree…

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