DOI: 10.1142/s0218625x0700958x
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Abstract: In the middle of the previous century, G. K. Boreskov, and J. Horiuti and S. Enomoto independently showed that for reversible reactions, running via a one-route mechanism with a ratelimiting step, there exist general relationships between the reaction rates in the forward and backward directions and also between the corresponding apparent activation energies and reaction heat. Their treatments are formally applicable to gas-and liquid-phase reactions and also to heterogeneous catalytic reactions (HCR) occurrin… Show more

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