Biocatalysis in ionic liquids

Quantitative Structure–Property Relationship Studies on Ostwald Solubility and Partition Coefficients of Organic Solutes in Ionic Liquids

“…After defining the descriptor space for the solutes, the BMLR procedure 56 was used to find the best correlation between the descriptors and property. The BMLR selects the best two-parameter regression equations, then the best threeparameter regression equations, etc., on the basis of the highest R 2 and F values in a stepwise regression procedure. The result obtained by BMLR is the "best" representation of the property in the given descriptors pool.…”

“…Common Descriptor Models for log P. The same general procedure, as described above for log L,was performed on the log P data. Overall, just two highly significant descriptors, i.e., DPSA2 difference in CPSAs (PPSA2-PNSA2) ZefiroV PC d 2 and Minimum partial charge (ZefiroV) for all atom types d 12 contribute to all the eight models for log P (see SM-5a).…”

“…1 Ionic liquids have found potential applications in "green" chemistries, separation processes, and various catalytic reactions. [2][3][4] Experimental solubilities and infinite dilution activity coefficients, γ i ∞ , of solutes dissolved in ionic liquids are important properties, which describe solute-solvent interactions. These properties have practical applications in commercial processes involving chromatographic separations and liquid-liquid extractions.…”

Asymmetric Reductive Amination of Carbonyl Compounds by Using<i> N,N,N</i>-Tributylpropanaminium Based Novel Chiral Ionic Liquid

“…Among the room temperature ionic liquids, chiral ionic liquids are known to be attractive and important for their potential applications to chiral recognition such as asymmetric synthesis and optical resolution of racemates [17]. Room temperature ionic liquids have become the choice of chemists for green synthesis and also employed in a variety of reactions [18,19], including organometallic reactions [20] and bio-catalyzed reactions [21,22].…”

ew pyridazinium-based ionic liquids: An eco-friendly ultrasound-assisted synthesis, characterization and biological activity

“…[1][2] Based on their attractive properties, ILs were extensively employed as an alternative green solvent to the common organic solvents. 3 Furthermore, ILs have been used in a broad range of applications in a variety of different fields, including the electrodeposition of metals 4 and the development of corrosion inhibitors, [5][6][7] as well as numerous applications in polymer science and catalysis. [8][9] On the basis of these findings, a series of novel functionalized pyridazinium-based ILs 1-7 is communicated using an efficient green ultrasound-assisted reaction.…”