The Porphyrins 1979
DOI: 10.1016/b978-0-12-220106-6.50013-9
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Cited by 173 publications
(140 citation statements)
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“…Meso-BR III␣ was kindly provided by Dr. D. A. Lightner (University of Nevada, Reno, NV). BR XIII␣ was prepared by acid scrambling of commercially obtained BR (7,9).…”
Section: Methodsmentioning
confidence: 99%
“…Meso-BR III␣ was kindly provided by Dr. D. A. Lightner (University of Nevada, Reno, NV). BR XIII␣ was prepared by acid scrambling of commercially obtained BR (7,9).…”
Section: Methodsmentioning
confidence: 99%
“…Etiobilioverdin-IVγ 8 (1) and mesobiliverdin-XIIIα 8,12-bis-hexanoic acid dimethyl ester (2) 8b were chosen as standard biliverdinoid reaction substrates that are readily synthesized by pchloranil promoted self-coupling of easily available 9-CH 3 dipyrrinones, kryptopyrromethenone 8c,9 and xanthobilirubinic-8-hexanoic acid methyl ester, 8b respectively (Scheme 3). Verdin 1 has an all-alkyl pyrrole β-periphery and possesses sufficient solubility in common organic solvents for cleavage reactions in a homogeneous phase.…”
Section: Synthesis: 9-ch 3 To 9-h Dipyrrinonesmentioning
confidence: 99%
“…HCl (70 mL) and water (3 × 100 mL). After drying (Na 2 SO 4 ), filtration and evaporation of the solvent, the residue was purified by radial chromatography on silica gel using as gradient CH 2 C NMR δ: 8.6,9.2,14.4,16.0,17.90,17.92,27.1,93.5,97.5,104.1,125.0,128.7,129.3,136.0,139.2,140.1,145.3,147.3,164.9,165.6,172.1 ppm. 13 C NMR data from (CD 3 ) 2 SO are in Table 2.…”
Section: 8-mentioning
confidence: 99%
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“…It has also been postulated as one of the principle defense mechanisms in the serum against oxidative stress (5,6) and may have protective effects for the pulmonary, (7) , cerebral (8) , Hepatobiliary (9) , immunological and cardiovascular systems (1,3) . The concept of non conjugated bilirubin as a powerful antioxidant could be the answer, from a teleological point of view, to human necessities for producing bilirubin and not stopping the catabolic chain from heme to biliverdin (BV) like DOI: http://dx.doi.org/10.22192/ijcrms.2017.03.02.004 amphibian, reptiles and birds do (10) . Biliverdin is a hydrosoluble substance that is easily excreted into the bile without spending an extra amount of energy or using other enzyme systems such as biliverdin reductase to finally produce bilirubin, a substance that is insoluble in water.…”
Section: Introductionmentioning
confidence: 99%