2006
DOI: 10.1016/j.chemolab.2005.11.004
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Bayesian analysis of spectral mixture data using Markov Chain Monte Carlo Methods

Abstract: This paper presents an original method for the analysis of multicomponent spectral data sets. The proposed algorithm is based on Bayesian estimation theory and Markov Chain Monte Carlo (MCMC) methods. Resolving spectral mixture analysis aims at recovering the unknown component spectra and at assessing the concentrations of the underlying species in the mixtures. In addition to non-negativity constraint, further assumptions are generally needed to get a unique resolution. The proposed statistical approach assum… Show more

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Cited by 61 publications
(38 citation statements)
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“…Thus, the proposed Bayesian model with Gamma prior has the advantage of using a more flexible prior model and offers a well stated theoretical framework for estimating the hyperparameters σ 2 n Nz n=1 , {α p , β p , γ p , δ p } Nc p=1 which are also included in the Bayesian model with appropriate prior distributions [2,31]. Thus, by using Bayes' theorem and assigning appropriate a priori distributions to these hyperparameters, the whole a posteriori distribution, including the hyperparameters, is expressed as…”
Section: Bayesian Modelmentioning
confidence: 99%
“…Thus, the proposed Bayesian model with Gamma prior has the advantage of using a more flexible prior model and offers a well stated theoretical framework for estimating the hyperparameters σ 2 n Nz n=1 , {α p , β p , γ p , δ p } Nc p=1 which are also included in the Bayesian model with appropriate prior distributions [2,31]. Thus, by using Bayes' theorem and assigning appropriate a priori distributions to these hyperparameters, the whole a posteriori distribution, including the hyperparameters, is expressed as…”
Section: Bayesian Modelmentioning
confidence: 99%
“…The Bayesian approaches introduced in [81][82][83] have all the same flavor: The posterior density is build under a hierarchical Bayesian model, which assumes conjugate prior distributions for some unknown parameters, accounts for nonnegativity and full additivity constraints. A Gibbs sampler is then used to overcome the complexity of evaluating the resulting posterior distribution and aproximating the MMSE estimate.…”
Section: Methodsmentioning
confidence: 99%
“…It is shown in these reviews that the Bayes theorem has been applied for analysing chromatography, mass spectrometry, microbiology, metrology and forensic science data. The Bayes estimation theory and Markov chain Monte Carlo (MCMC) methods were also used for analysing the multicomponent spectral data and resolving the spectral mixtures [25].…”
Section: Introductionmentioning
confidence: 99%